DOI: https://doi.org/10.53056/2022-3(109)-2
CRYSTALOCHEMICAL AND SPECTROSCOPIC FEATURES OF BERYL FROM VOLYN AND VYBORG MASSIF (FINLAND) PEGMATITES
CRYSTALOCHEMICAL AND SPECTROSCOPIC FEATURES OF BERYL FROM VOLYN AND VYBORG MASSIF (FINLAND) PEGMATITES
V. Khomenko M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of NAS of Ukraine |
Franz Gerhard State Technical University of Berlin |
О. Belichenkо State Gemmological Centre of Ukraine |
Language: Ukrainian |
Precious and Decorative Stones. No. 3 (109), 2022: 9–14 |
Abstract Beryl samples from Ukraine (Volyn) and Finland (Luumäki), associated with miaroliticpegmatites in Proterozoic rapakivi granites were studied by electronic microprobe analysis, X-ray diffraction, optical and infrared (IR) spectroscopy. Previous studies demonstrated the similarity of their crystallization conditions, physical parameters, inclusions and gemological characteristics. |
Keywords: beryl, crystal chemistry, IR spectra, inclusions, chamber pegmatites. |
References |
1. Simonen A. Geological map of Finland 1:100 000. The Pre-Quaternary rocks of the map-sheet areas of the rapakivi massif in SE Finland.
Geological Survey of Finland. Helsinki. 1987. 49 p. ISBN 951-690-250-2.
2. Lyckberg P. Ein Neufund phantastischer grüner Edelberylle aus Luumäki, Karelien, Finnland. Mineralien-Welt. 2004. 6. Р. 38–45. 3. Vaasjoki M. Rapakivi granites and other postorogenic rocks in Finland: their age and the lead isotopic composition of certain associated galena mineralizations. Geological Survey of Finland. Bull. 1977. 294. 64 р. 4. Integrated geological and economic assessment of raw gems within the Volodarsk-Volynsk chambered pegmatite deposit: report on Scientific research work (interim) SGCU; head O. Belichenko. Kyiv, 2013. 88 p. [in Ukrainian] 5. Lazarenko E.K., Pavlishin V.I., Latysh V.T., Sorokin Yu.G. Mineralogy and genesis of chamber pegmatites of Volyn: monograph. Lvov: Vishcha shkola, 1973. 359 p. [in Russian] 6. Vozniak D.K. On Determination of Formation Depth of Volyn Chamber Pegmatites and Thickness Estimation of Their Expansion Zone with Depth. Mineralogical Journal. 2003. 25, № 1. P. 43–49. [in Ukrainian] 7. Vozniak D.K., Pavlyshyn V.I. Physic-Chemical Conditions of Formation and Peculiarities of Location of Volyn Chamber Pegmatites (Ukrainian Shield). Mineralogical Journal. 2008. 30, № 1. P. 5–20. [in Ukrainian] 8. Vozniak D.K., Khomenko V.M., Franz G., Wiedenbeck M. Physic-Chemical Conditions of the Late Stage of Volyn Pegmatite Evolution: Fluid Inclusions in Beryl Studied by Thermobarometry and IR Spectroscopy Methods. Mineralogical Journal. 2012. 34, № 2. P. 26–38. [in Ukrainian] 9. Kinnunen K.A. Luumäen jaloberyllin sulkeumatutkimus, gemmologiset ominaisuudet ja kuvaopas tyyppisulkeumista. Geologian tutkimuskeskus. 1991. P. 1–33. 10. Kinnunen K.A., Lindqvist K., Lahtinen R. (1987) Fluid history from crystal cavities in rapakivi (granite), Pyterlahti, southeastern Finland. Bull. Geol. Surv. Finland. 1987. 59, Part 1. Р. 35–44. 11. Khomenko V.M., Vyshnevskyy O.A., Gnelytska Z.T., Kamenchuk V.K. Crystal Chemistry of Beryl from Volyn Deposit on the Basis of Microprobe Analyses Optical and IR-Spectroscopic Data. Mineralogical Journal. 2007. 29, № 3. P. 70–81. [in Ukrainian] 12. Lahti S.I., Kinnunen K.A. A new gem beryl locality: Luumaki, Finland. Gems & Gemology. 1993. 29. Р. 30–37. 13. Aurisicchio C., Grubessi O., Zecchini P. Infrared spectroscopy and crystal chemistry of the beryl group. Can. Mineral. 1994. 32. P. 55–68. 14. Platonov A.N., Khomenko V.M., Taran M.N. Crystal Chemistry, Optical Spectra and Color of Beryl. I. Heliodor and Golden Beryl — Two Varieties of Natural Yellow Beryl. Mineralogical Journal. 2016. 38, № 2. P. 3–14. [in Russian] 15. Platonov A.N., Taran M.N., Minko O.E., Polshyn E.V. Optical absorption spectra and nature of color of iron-containing beryls. Phys. Chem. Minerals. 1978. V. 3. P. 87–88. 16. Fukuda J., Shinoda K. Coordination of water molecules with Na+ cations in beryl channel as determined by polarized IR spectroscopy. Phys. Chem. Minerals. 2008. 35. P. 347–357. 17. Aines R.D., Rossman G.R. The high temperature behavior of water and carbon dioxide in cordierite and beryl. Amer. Mineral. 1984. 69. P. 319–327. 18. Barres O., Burneau A., Dubessy J., Pagel M. Application of micro-FT-IR spectroscopy to individual hydrocarbon fluid inclusion analysis. Applied Spectroscopy. 1987. 41, 6. P. 1000–1008 |